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Beilstein J. Org. Chem. 2021, 17, 2611–2620, doi:10.3762/bjoc.17.174
Graphical Abstract
Figure 1: Structures of the steroidal tetrazoles that showed anticancer potential in vitro.
Figure 2: Mechanism of the Schmidt reaction.
Scheme 1: Synthesis of 12-oxo intermediates. Reagents and conditions: a) EtOAc, pTsOH, reflux, 14 h (81%); b)...
Scheme 2: Synthesis of 7-oxo intermediate 11 from chenodeoxycholic acid (9). Reagents and conditions: a) EtOA...
Figure 3: Mercury [51] drawing of the molecular structures of compounds 13 and 14, with labelling of nonhydrogen ...
Figure 4: Dose dependence of the cytotoxicity of tested compounds on treated cell lines. All compounds were t...